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CARBOHYDRATES - Monosaccharides


Carbohydrates are considered as the most abandunt organic matter. The things we meet up as sugars and flour in day-to-day life belong to the group of Carbohydrates. All Carbohydrates have the general formula: Cx(H2O)y. Carbohydrates can be divided into 3 classes;


  • Monosaccharids
  • Disaccharides
  • Polysaccharides

MONOSACCHARIDES
Monosaccharides are the building blocks of other Carbohydrates. Their molecular structures are simple. They show the following characteristics in common;
  1. Sweet in taste
  2. Soluable in water
  3. Can be crystellined(Can be made into crystals)
  4. General formula is (CH2O)n
  5. Show reducing properties (Monosaccharides are reducing sugars)

Reducing Sugars?
All the monosaccharides are reducing sugars. They can reduce Benedict's Solution. Benedict's Solution contains Cu2+ ions, which are blue in colour. Monosaccharides reduce Cu2+ ions to Cu+ ions, which gives "brick-red clour" to the solution.

Monosaccharides are classified according to the number of Carbon(C) atoms in the molecule.

3  Carbon atoms -> Triose [Eg: Glyceraldehyde]
4  Carbon atoms -> Tetrose [Eg: Erythrose]
5  Carbon atoms -> Pentose [Eg: Ribose]
6  Carbon atoms -> Hexose [Eg: Glocose]

Of these, Pentoses and Hexoses are the most common.

Aldoses and Ketoses
In all monosaccharides, all the Carbon(C) atoms, except one, have hydroxyl groups(-OH) attached to them. The Carbon(C) atom which has no hydroxyl group(-OH) is either a part of an Aldehyde group, or a part of a Keto group. In case of an aldehyde group, the sugar is called an Aldose or an Aldo Sugar. In case of a keto group, the sugar is a Ketose or a Keto Sugar.



Ring Structures
Pentoses and Hexoses are longer molecules. Due to the bond angles of Carbon(C) atoms, the sugar molecule bends: forming a stable ring structure.
Formation of the Ring Structure of Glucose
The first Carbon atom(C1) combines with the Oxygen atom of the fifth Carbon atom(C5)

In Pentoses, the first Carbon atom(C1) combines with the Oxygen atom of the fourth Carbon atom(C4)

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